Converting between liters and moles is a fundamental calculation in chemistry, especially when dealing with gases. This conversion relies on the ideal gas law, which describes the relationship between pressure, volume, temperature, and the number of moles of a gas.
The ideal gas law is expressed as:
\[ PV = nRT \]
Where:
To convert from liters to moles, we rearrange the equation to solve for n:
\[ n = \frac{PV}{RT} \]
To convert from moles to liters, we rearrange the equation to solve for V:
\[ V = \frac{nRT}{P} \]
Let's calculate the number of moles of a gas that occupies 5.0 L at 2.0 atm and 300 K:
Given:
Step 1: Identify the formula
We're calculating the number of moles, so we'll use: n = PV / RT
Step 2: Substitute the values
n = (2.0 atm * 5.0 L) / (0.08206 L⋅atm⋅K^−1⋅mol^−1 * 300 K)
Step 3: Solve the equation
n = 10 / 24.618 = 0.406 moles
Therefore, 5.0 L of the gas at 2.0 atm and 300 K contains 0.406 moles.
The following diagram illustrates the relationships between pressure, volume, temperature, and number of moles in the ideal gas law:
This diagram shows how the variables in the ideal gas law are interrelated. As one variable changes, the others must adjust to maintain the equality PV = nRT. For instance, if temperature increases while pressure remains constant, the volume must increase proportionally.